DOI Number : 10.5614/itbj.sci.2012.44.1.4
Hits : 10

Synthesis, theoretical study on Zinc (II) and Ni(II) complexes of 5-methoxyisatin 3-[N-(4-chlorophenyl) thiosemicarbazone]

Fatma Kandemirli1, Murat Saracoğlu2, Gamze Bulut3, Eno Ebenso4, Taner Arslan5 &Asgar Kayan3

1Department of Chemistry, Niğde University, 51240, Niğde, Turkey
2Faculty of Education, Erciyes University, 38039, Kayseri, Turkey
3Department of Chemistry, Kocaeli University, 41380, Izmit, Turkey
4Department of Chemistry, North West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa
5Department of Chemistry, Osmangazi University, 26480, Eskişehir, Turkey


Zinc(II) and nickel(II)-complexes of 5-methoxyisatin 3-[N-(4-chlorophenyl) thiosemicarbazone] (H2MICP) were synthesized and characterized by infrared, ultraviolet and 1H-NMR spectroscopies as well as elemental analysis. Model of H2MICP and its zinc(II) and nickel(II)-complexes were optimized with B3LYP method using 6-31G(d,p), 6-311G(d,p), 6-311++G(d,p), 6-311++G(2d,2p) basis sets. The calculated 1H-NMR, UV and IR spectra data were compared with experimental results. In addition to the Natural Bond Orbital (NBO) analysis of H2MICP and its Zinc(II) and Nickel(II) complexes, Fukui functions of H2MICP were also reported.

Keywords: DFT; isatin thiosemicarbazones; Zn (II) and Ni (II)-complexes

Download Article
Bahasa Indonesia | English


Begin on 10 October 2014 this website is no longer activated for article process in Journal of Mathematical and Fundamental Sciences, Journal of Engineering and Technological Sciences, Journal of ICT Research and Applications and Journal of Visual Art and Design. The next process will be proceeded under new website at

For detail information please contact us to:

       ITB Journal Visitor Number #24518372       
       Jl. Tamansari 64, Bandung 40116, Indonesia Visitor IP Address #       
       Tel : +62-22-250 1759 ext. 121 2011 Institut Teknologi Bandung       
       Fax : +62-22-250 4010, +62-22-251 1215 XHTML + CSS + RSS       
       E-mail : or Developed by AVE