DOI Number : 10.5614/itbj.sci.2011.43.3.5
Hits : 5

Band Alignment and Optical Properties of (ZrO2)0.66(HfO2)0.34 Gate Dielectrics Thin Films on p-Si (100)

Dahlang Tahir1, Hee Jae Kang2 and Sven Tougaard3

1Department of Physics, Hasanuddin University, Makassar, 90245, Indonesia
2Department of Physics, Chungbuk National University, Cheongju, 361-763, Korea
3Department of Physics and Chemistry, University of Southern Denmark, DK-5230 Odense M. Denmark
Email: d.tahir@fmipa.unhas.ac.id


Abstract.

(ZrO2)0.66(HfO2)0.34 dielectric films on p-Si (100) were grown by atomic layer deposition method, for which the conduction band offsets, valence band offsets and band gaps were obtained by using X-ray photoelectron spectroscopy and reflection electron energy loss spectroscopy. The band gap, valence and conduction band offset values for (ZrO2)0.66(HfO2)0.34 dielectric thin film, grown on Si substrate were about 5.34, 2.35 and 1.87 eV respectively. This band alignment was similar to that of ZrO2. In addition, The dielectric function ε (k, ω), index of refraction n and the extinction coefficient k for the (ZrO2)0.66(HfO2)0.34 thin films were obtained from a quantitative analysis of REELS data by comparison to detailed dielectric response model calculations using the QUEELS-ε (k,ω)-REELS software package. These optical properties are similar with ZrO2 dielectric thin films.



Keywords: Band alignment; band gap; gate dielectrics; REELS; XPS.

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